Technical Proceedings of the 2010 Clean Technology Conference and Trade Show

Clean Technology 2010

Chapter 7: Water, Waste, Emissions & Remediation

Authors:
R.-A. Khan, R. Sharma
Affilation:
Manav Rachna International University, IN
Pages:
387 - 390
Keywords:
anticorrosive plastics, arsonium, nanomaterials, antibacterial woods
Abstract:
A search of anticorrosive with antibacterial property of compounds motivated us to synthesize nanomaterials with quaternary compounds. The arsonium triiodides [(Ph3AsCH2I]I3 and [(i-Bu)3AsCH2I]I3 nanomaterials have been synthesized and characterized. The x-ray structures of [(Ph3AsCH2I]I3 and [(i-Bu)3AsCH2I]I3 have been determined. Crystals belong to the monoclinic (comp.1) system, space group P 21/n (No. 14) with a = 10.97 (1)Å, b=13.152 (1)Å, c=16.882 (1)Å , β=93.01 (1)o and to the triclinic system (comp.2), space group P-1 (No. 2) with a=8.413 (1)Å, b=9.109 (1)Å, c=15.876 (1)Å, α = 76.24 (1)o , β=75.60 (1)o, γ=75.26 (1)o. The structures were refined to an R value of 0.063 from 4082 (comp. I) and 0.091 from 4475 (comp.2) observed reflections. The As atom is coordinated tetrahedraly to the substituents and the anion has a linear structure. The synthesis of [R2(R’)AsCH2I]I3 (where R= R’ or R≠ R’) are described. The antibiocorrosive woods and plastics have possibility of the perspective application in synthesized compounds in bacterial resistant structures in homes and buildings. The test-microorganisms such as phitogen gram-positive - Staphylococus aurous, from gut’s group bacteria phitogen gram-negative - Esherichia coli, spore-forming bacteria – gram-positive Bacillus subtilis and gram-positive (from radiate mushrooms) Autinomyces griseus showed high toxicity of iodmethylenediamylphenylarsonium triiodide as antibacterial nanomaterials. It inhibited growth of Esherichia coli, Staphylococus aureus and Bacillus subtilis with minimal concentrations.
Antibiocorrosive Woods and Plastics Nanomaterials :Arsonium triiodides and Silicon Organic matrix
ISBN:
978-1-4398-3419-0
Pages:
482